1 Introduction. Hematite (α-Fe 2 O 3) is a naturally abundant and important magnetic mineral in paleomagnetism, rock magnetism, and environmental magnetism.Although its magnetic properties have been investigated extensively, first-order reversal curve (FORC) diagrams (Pike et al., 1999; Roberts et al., 2000) have yet to be studied in detail for …
The world-class El Laco iron deposit in the ELVC consists of six massive magnetite ore bodies that are spatially associated with the pre-existing subvertical annular collapse structures and ...
Clay minerals can also lead to reduction of hematite to magnetite by releasing Fe 2+; details of the chemical reactions involved require further study (C. Zhang et al., 2012; Jiang, Liu, Zhao, ... (Figure 2) indicate that the spectrum is consistent with emission dominated by the crystallographic c-faces of platy hematite (Lane et al., 2002), ...
Clay minerals can also lead to reduction of hematite to magnetite by releasing Fe 2+; details of the chemical reactions involved require further study (C. Zhang et al., 2012; …
Chicot, D. et al. Mechanical properties of magnetite (Fe3O4), hematite (α-Fe2O3) and goethite (α-FeOOH) by instrumented indentation and molecular dynamics analysis. Mater. Chem.
As an example, Zhao et al. reported that the transformation from magnetite to hematite under hydrothermal conditions depends on the solubility of ferrous species. 17 The oxidation of magnetite in air is primarily affected by the ambient temperature, 18 such that the oxidation kinetics increase along with temperature. At lower temperatures (<300 ...
Magnetite and hematite are two forms of iron ores from which iron can be extracted. Magnetite contains iron in the form of Fe 3 O 4. Hematite contains iron in the form of Fe …
The transformation between iron oxide minerals is one of the most common phenomena in a geologic system. It can be chemically described as a reversible reaction and can be …
Muxworthy et al. measured FORC diagrams for artificial magnetite/hematite mixtures and found critical concentrations at which the magnetite signal swamped the hematite signal, rendering the hematite undetectable. They found that when hematite was less than ∼81% of the mixture by mass, it was barely detectable using FORC diagrams.
1. Introduction. The replacement of magnetite by hematite is commonly observed in various geologic systems, especially in banded iron formations (BIF), iron oxide copper-gold deposits, and iron skarn deposits (Angerer et al., 2012; Franchini et al., 2000; Ehrig et al., 2021).The transformation of magnetite to hematite was attributed to an oxidizing …
In the case of the sorption of arsenic on hematite, Xu et al. [17] observed a decrease of the sorption of As(V) with the increase of pH. Singh et al. [18] also studied the sorption of As(V) on a natural hematite, they found that the sorption followed first-order kinetics and the data fitted a Langmuir isotherm. The variation of the sorption ...
Converting hematite to magnetite in Bayer liquor at elevated temperature plays a key role in the exploration of a cleaner technology for alumina production with high iron content bauxite. In this work, the effects of Si-bearing minerals on hematite conversion during reductive Bayer digestion were investigated by studying the reaction kinetics ...
The replacement of magnetite by hematite was also observed from the cross-sections of the partially reacted grains under back-scattered SEM. After 2-day reaction at 200 °C in A4 buffer solution (Run A1), hematite was observed along the outer edge of the magnetite grains (Fig. 3 A).The newly formed hematite layer was not evenly distributed around the …
The kinetics aspect of hematite–magnetite transformation is partly considered by Abdouni et al. (1988) and Chakraborty (1999). Although hematite to magnetite reduction is …
Magnetite and hematite are common iron-oxides, being found in sedimentary, metamorphic and igneous environments and ... (2003) (Prominent Hill) and Esdale et. al. (2003) (Olympic Dam). Nelson and Van Voorhis (1983), in a field study using small electrode spacings, measured the IP effects of disseminated magnetite, finding …
Hillert et al. [1] recently analyzed the diffusion-controlled growth of an external phase with a fixed composition, i.e. a stoichiometric phase. In the present article models for diffusion in the iron oxides Fe 3 O 4, and Fe 2 O 3, i.e. magnetite and hematite, respectively, are proposed. Magnetite has the spinel structure with a considerable ...
The transformation of weakly magnetic hematite to magnetite is a promising technique that can enhance the efficiency of magnetic separation of hematite quartzite. The transformation of hematite into magnetite involves the partial reduction of Fe(III) to Fe(II) and converting the rhombohedral crystal system of hematite into cubic of magnetite.
DOI: 10.1016/J.MSEB.2013.03.011 Corpus ID: 97850107; Magnetite–hematite nanoparticles prepared by green methods for heavy metal ions removal from water @article{Ahmed2013MagnetitehematiteNP, title={Magnetite–hematite nanoparticles prepared by green methods for heavy metal ions removal from water}, author={M. A. …
Woo et al. created a novel and cheap synthetic procedure, which is a combination of the sol–gel reaction in reverse micelles and crystallization by reflux for the preparation of hematite and maghemite nano-rods: the rod-shaped hematite (the ferromagnetic behavior from 5 to 300 K, H C = 53 Oe, M r = 0.28 emu/g at room temperature) (Fig. 5 a ...
In view of the striking discrepancies among previous authors as regards the transition between porous and lamellar magnetites, we have carried out a wide series of experiments with single crystals prepared by chemical vapor transport. In addition to the classical temperature and CO pct parameters, which varied over a large range (400 ≤T ≤ 1000 ≤C …
Hematite is an iron oxide with the chemical formula Fe2O3; magnetite is also an iron oxide but with the chemical formula Fe3O4. Another important difference between hematite and magnetite is that hematite appears in a variety of colors, but magnetite is only black in …
Extra-lunar contamination, fumarolic activity, and exposure to oxidizing gases from comet or carbonaceous meteorite impacts have been previously proposed as the causes of magnetite, hematite, and goethite in lunar materials. However, these minerals can occur in the stable low temperature gas-solid equilibrium assemblages of lunar rocks.
We used crystal structure data from quartz (Lignie et al., 2012), muscovite (Gatineau, 1963), chlorite (Zheng & Bailey, 1989), albite (Ribbe et al., 1969), hematite (Blake et al., 1966), and magnetite (Fleet, 1986) as input sources. The compositions of these minerals were adjusted to those of our samples by changing the site occupancies of atoms.
a Series I samples (I-0, I-2, I-4, I-8, I-16) were transformed from hematite samples HFh* series, which have been investigated by Jiang et al.[], and series II samples (II-0, II-4, …, II-20) were transformed from hematite samples Hm* series from Jiang et al[]The unit cell parameter a was calculated based on XRD data. Particle size was measured based on …
Hematite is an iron oxide mineral with the chemical formula Fe2O3, while magnetite is also an iron oxide mineral but has a chemical formula of Fe3O4. The main difference …
It was found that most of the Raman bands corresponded to those of the hematite (α-Fe 2 O 3 ). The characteristics Raman bands reported for hematite are 227, 293, 409, 498, 611, 658 and 1320 cm ...
The characteristics and mechanism of phosphate adsorption onto magnetite, hematite and goethite were comparatively studied, and the effects of magnetite, hematite and goethite amendment and capping on endogenous phosphorus (P) liberation from sediment into overlying water (OW) were comparatively investigated. The adsorption of phosphate …
The literature review have shown that hematite transforms to magnetite at a good reaction rate in an atmosphere containing 20% CO (Monazam et al., 2014), and 40% CO (Chen …
The mechanism and kinetics of the reduction of hematite to magnetite in a laboratory-scale, micro-fluidized bed reactor were isothermally investigated. ... Trushenski et al. Hematite/10%CO-CO 2: Isothermal (750–800 °C) 69–100: Non-topochemical model : Piotrowski et al. Hematite/5.7%CO + 4.3%H 2-N 2: Isothermal (700–900 °C) 58.13: …
Abstract—First results of the experimental study of a hydrothermal multisystem including lanthanides (Ln) and Fe oxides (magnetite and hematite) are presented.Ln concentrations in solutions and crystals were determined by ICP-MS and LA-ICP-MS, respectively. The Ln partition and cocrystallization coefficients obtained are interpreted as the maximum …
Quand on parle de pierres précieuses, l'hématite n'est peut-être pas la première chose qui vient à l'esprit. Cependant, sous son aspect sombre, la pierre hématite recèle un riche potentiel.L'hématite est une pierre d'oxyde de fer à l'aspect sombre et métallique. Cependant, lorsqu'il est coupé ou ébréché, il prend une teinte rouge vif.
The slope of the hematite–χ FD regression line for the Russian soils was smaller for the soils from areas with the higher rainfall. The average slope of the regression lines in Figure 1 is ∼0.4 g hematite kg −1 /10 −8 m 3 kg −1. This value is equivalent to a mass ratio between hematite and magnetite/maghemite of ∼4.
Hematite phase is the oxide with the highest oxygen content, followed by magnetite. The ideal stoichiometries of hematite and magnetite are Fe 2 O 3 and Fe 3 O 4, respectively. Theoretically, magnetite is in equilibrium with hematite at low temperature. There are two small magnetite-phase stable areas at high temperatures.
Furthermore, unlike hematite, magnetite deposits are less prone to impurities such as phosphorous and sulfur. Considering both the pros and cons of hematite and magnetite extraction methods and geological occurrence can help you make an informed decision on which ore type would work best for your specific application. So whether you're ...
The ilmenite-hematite (FeTiO 3-Fe 2 O 3) solid solution (Ilm ss) commonly occurs in layered intrusions (Harrison et al. 2000).Ilm ss tends to experience subsolidus re-equilibration and phase transformation during different T-f O 2 cooling paths, forming hematite and/or magnetite exsolution and magnetite-rutile intergrowths in ilmenite …
Surface Chemistry. Magnetite is amphoteric, i.e., it can behave as an acid or a base. The reactive sites at the surface are hydroxyl groups (−OH) and the density of groups has been measured as 5 per square nanometer (Parkinson et al. 2012).Freshly ground natural magnetite has a pH of 6.5 (Milonjić et al. 1983).Organosilanes, titanates, sulfonates, …